I ordered some wine through Prime Now last month. I fully expected to have to show ID, so when I got the notification that the delivery was on its way I went to Bell Services. Turned out the delivery person had just left, but all my stuff was there, including the box of wine. So, no ID from me. Obviously, other people’s experience may vary.
Of course, the nice thing with Prime Now is that they have two hour delivery, so super easy to schedule it for a time when you know you’ll be there.